


|
General Description |
(S)-(-)-Perillaldehyde is a monoterpene aldehyde mainly found in the herb, Perilla frutescens. It is the key volatile flavor compound of orange juice and mandarin peel oil. |
InChI:InChI=1/C10H14O/c1-8(2)10-5-3-9(7-11)4-6-10/h3,7,10H,1,4-6H2,2H3/t10-/m1/s1
A facile route to perillyl alcohol (POH)...
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(-)-(S)-limonene
Carvone
1-methyl-4-isopropenylbenzene
L-carveol
(S)-(-)-perillaldehyde
| Conditions | Yield |
|---|---|
|
With
tert.-butylhydroperoxide; air; iron(III) chloride;
In
acetic acid; acetonitrile;
Product distribution;
picolinic acid, time, atmosphere;
|
8.9% 1.1% 1.2% 1.4% |
(-)-perillyl alcohol
(s)-(-)-perillic acid
(S)-(-)-perillaldehyde
| Conditions | Yield |
|---|---|
|
With
tert-butyl 1-hydroxy-2-methyl-6-trifluoromethyl-1H-indole-3-carboxylate; oxygen; copper(l) chloride;
In
N,N-dimethyl-formamide;
at 50 ℃;
for 24h;
under 760.051 Torr;
|
65% 13% |
|
With
Acetobacter sp. MIM 2000/61;
In
water;
at 28 ℃;
for 2h;
pH=7.5;
phosphate buffer;
Enzymatic reaction;
|
(-)-perillyl alcohol
(-)-(S)-limonene
(4S)-7-nitromentha-1,8-diene
(S)-1-(chloromethyl)-4-(prop-1-en-2-yl)cyclohex-1-ene
(-)-perillyl alcohol
(1R,6S)-7,7-dimethylbicyclo[4.1.0]hept-2-ene-3-carboxaldehyde
(1S,3R)-1-Isopropenyl-3-methoxy-cyclohexane
(1R,2S,4S)-4-Isopropenyl-2-methoxy-cyclohexanecarbaldehyde
