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D-Glucurono-6,3-lactone is a glucuronic acid derivative studied for its effectiveness against canine hepatitis. It is utilized in the studies such as starting regent in the synthesis of 2,3,4,-tris(tert.-butyldimethysilyl) glucuronic acid trichloroethylester, required for the preparation of 1-O-acyl glucuronide of the anti-inflammatory drug ML-3000, synthesis of optically active glucopyranoses, synthesis of long-chain alkyl glucofuranosides.
3-O-α-L-rhamnopyranosyl-(1→2)-β-D-glucuronopyranosyl-(1→2)-β-D-glucuronopyranosyl-22-O-α-L-rhamnopyranosyl-squasapogenol
L-Rhamnose
D-glucurono-6,3-lactone
| Conditions | Yield |
|---|---|
|
With
water; trifluoroacetic acid;
for 2h;
Reflux;
|
3-O-α-L-rhamnopyranosyl-(1→2)-β-D-glucuronopyranosyl-(1→2)-β-D-glucuronopyranosyl-macedonic acid
L-Rhamnose
D-glucurono-6,3-lactone
| Conditions | Yield |
|---|---|
|
With
water; trifluoroacetic acid;
for 2h;
Reflux;
|
The CAS number of D-Glucurone is 32449-92-6.
More information of D-Glucurone 32449-92-6 are:
|
CAS Number |
32449-92-6 |
|
Density |
1.749 g/cm3 |
|
Melting Point |
172-175 °C(lit.) |
|
Boiling Point |
403.5 °C at 760 mmHg |
|
Flash Point |
174.9 °C |
|
Vapor Pressure |
1.31E-11mmHg at 25°C |
|
Refractive Index |
18.5 ° (C=5, H2O) |
|
HS CODE |
29322980 |
|
PSA |
104.06000 |
|
LogP |
-2.80660 |
|
Pka |
11.96±0.60(Predicted) |
Synonyms for D-Glucurone 32449-92-6:Glucuronicacid, g-lactone, D- (6CI,8CI);D-Glucuronic acid lactone;D-Glucurono-3,6-lactone;D-Glucurono-g-lactone;D-Glucuronolactone;Dicurone;Glucoxy;Glucurone;D-Glucuronic acid, gamma-lactone;Glucuronolactone;Glucuronosan;Glycurone;Guronsan;NSC 656;
The chemical formula of D-Glucurone is C6H8O6 which containing 6 Carbon atoms,8 Hydrogen atoms and 6 Oxygen atoms,and the molecular weight of D-Glucurone is 176.126.
D-(+)-Glucuronic acid γ-lactone, also known as D-Glucurone, Glucourono-γ-lactone, or Glycurone, is a carbohydrate derivative found in plant gums and animal connective tissues. It is a white crystalline substance with a unique crystal structure that has been studied. D-Glucurone is notable for its conversion into L-ascorbic acid, also known as vitamin C, in animals and the human body. Its molecular structure contains two five-membered rings, which contribute to its chemical properties and potential applications.
InChI:InChI=1/C6H8O6/c7-1-3-4(12-5(1)9)2(8)6(10)11-3/h1-5,7-9H/t1-,2-,3-,4-,5-/m1/s1
Relevant articles related to D-Glucurone:
|
Article |
Source |
|
- |
Graefe , p. 205,208 (1953) |
|
Field survey of glycyrrhiza plants in Central Asia (5). Chemical characterization of G. Bucharica Collected in Tajikistan |
Hayashi, Hiroaki,Yokoshima, Keiko,Chiba, Ren,Fujii, Isao,Fattokhov, Inoyat,Saidov, Madibron , p. 534 - 539 (2019/07/22) |
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